Caution: Bad Word Ahead – Corrosion!
As our membership grows, so does the shared technical information of our collective group. Educational article links, like this article on corrosion, are always available on our website.
SHERRY STEPP, PRESIDENT, MCA
No matter where you are, there are certain times of the year when humidity increases and if you are working with untreated metal, you probably have had an issue with corrosion or rust. Understanding what happens to that metal part next is always the deciding factor of how you deal with it. How clean does it have to be? Can it be too clean? Will it be painted or treated? How will it ship? Navigating the options can be a little intimidating and finding a trusted source is where being a member of the MCA is a big benefit.
We have posted a new paper in our Technical Resources section titled Corrosion Prevention Procedures for Metal Parts to help turn those bad words into good words like long-term protection and prevention. As our membership grows, so does the shared technical information of our collective group, meaning you can get exclusive access these resources any day, any time.
Bubble, Bubble, Toil and Trouble – Solvent Wins and Losses
May 17, 2022, 11 a.m. EDT
This webinar will cover why solvent cleaning works so well for some soils and surfaces, how solvent blends are created, how to manage flammability risks, and how to reduce worker exposure. There will be a good mix of introductory and advanced material to benefit attendees of all skill levels. Comparisons to aqueous cleaning will be made, and we will discuss the recent and ongoing action of the EPA in the area of solvent cleaning risk assessment. Presented by Darren Williams, Ph.D., Sam Houston State University
KYZEN Corp. provides environmentally responsible precision cleaning chemistries for industries ranging from electronics and advanced packaging to metal finishing and aerospace applications.
North America: 1-615-831-0888
Europe: +32 50 395 374
Southeast Asia: +60-4-630-3000
China: +86 21 5998 7189
About Us: KYZEN is a global leader in providing environmentally responsible precision cleaning chemistries for industries ranging from electronics and advanced packaging to metal finishing and aerospace applications. Since 1990, our innovative cleaning technologies, scientific expertise and customer support have been repeatedly recognized with the industry’s most prestigious awards.
Our Team: Our global reach spans over 49 countries, 144 cities and growing with over 300 team members. Each team member has a dedication to excellence, a mind for scientific innovation and a desire to ensure your cleaning process performs successfully – anywhere in the world.
Our products/services: Whether you are seeking environmentally friendly cleaning products, cleaning advice and support, or advanced cleaning technologies and accessories, we provide everything you need to run reliably and efficiently. Our chemistries and process control line were created with your needs in mind from start to finish.
Awards and Recognition: KYZEN has been honored with nearly 100 prestigious industry awards in categories including New Product Innovation, Environmental, Best Cost of Ownership, and the Customer Service Award, for 15 years consecutively.
Testimonials: “I have tested and used several of the products (comparing to competitors) and in my opinion KYZEN regularly out-performed the competition. They have a strong technical staff and can dial in a specific product recommendation to match needs/situations. They are always willing to perform testing in their laboratory or send technical experts to our facility as required. No customer appears to be too small or too large for them to provide excellent service.” – Bill Vuono, Qorvo
“The cleaning agent meets our strictest customer cleanliness objectives and expectations. Customer service is exceptional, and the engineering support is top class-very responsive! Technology is important and staying ahead of the technology curve is important. KYZEN is always pushing and building new solutions continuously.” – Mark McMeen, STI Electronics
“We are absolutely thrilled with the results we are achieving with KYZEN products and have no need or desire to change. Each time we have faced a new challenge they have been able to respond with a process or product solution.” Chris Reddy, Xanfab Inc.
How EPA Decisions Might Affect Surface Preparation
Originally published by Production Machining and Products Finishing
In 2020, the EPA determined that four degreasing solvents used in parts cleaning pose “unreasonable risks” to workers. By the end of 2022, there should be new rules outlining restrictions on how the solvents can be used. Solvent bans are possible. What should surface finishing companies do?
Last year, the EPA determined that four degreasing solvents used in parts cleaning pose “unreasonable risks” to workers. By the end of 2022, there should be new rules outlining restrictions on how the solvents can be used. Solvent bans are possible. What should surface finishing companies do?
The U.S. Environmental Protection Agency (EPA) is moving expeditiously toward actions that could restrict the availability and costs of cleaning agents that the world of surface finishing has come to depend on. Some suppliers of cleaning agents and cleaning machines have been quick to forecast complete solvent bans and to urgently suggest that potential customers immediately change the cleaning process to one using their product offerings. No one can predict what steps the EPA will take; final decisions have not been made. While it is tempting to assert that all fabricators and surface finishers must immediately hire critical cleaning consultants, a proactive approach is suggested. This involves becoming educated about various cleaning options and progress of regulatory activities. Many sources of information are available; it is important to read critically, evaluate critically and clean critically.
The EPA is moving relatively rapidly because, in 2016, the Frank R. Lautenberg Chemical Safety for the 21st Century Act became law with broad-based congressional support. The law amends the Toxic Substances Control Act (TSCA). Traditionally, the EPA looked primarily at impacts on the environment. The new law (sometimes referred to as “Lautenberg” or “TSCA Reform”) brings the EPA further into the field of worker exposure, an area that had been previously considered to be the purview of the Occupational Safety and Health Association (OSHA). Among other things, the law mandates the EPA to review the uses of existing chemicals for unreasonable risks to human health or the environment. By the end of 2020, the EPA issued a final risk assessment on the first 10 chemicals that it considers as the highest priority, including four degreasing solvents: methylene chloride (MC), trichloroethylene (TCE), perchloroethylene (PCE), and n-propyl bromide (nPB).
The concern, particularly for product manufacturers, is that the EPA finds “unreasonable risks” to workers for all four cleaning agents as they would be used in vapor degreasing operations. An additional degreasing solvent, trans-1,2-dichloroethylene (trans-DCE), has not yet been evaluated for risks but will be in the next tier of prioritized chemicals.
Once a risk assessment has been finalized, the EPA must propose a rule to mitigate the risks within one year and finalize the rule within two years. That means that all four solvents are mandated to have final rules in place by the end of 2022. Final rules may include a timeline for developing and implementing process changes, process controls or bans.
Many manufacturers think that because plating and anodizing use water-based processes, surface preparation before finishing can use aqueous cleaning, not solvents. However, for the aqueous processes in surface finishing to be successful, the residue of metalworking fluids must first be thoroughly removed from parts. This is easier said than done. Creating the product to be plated involves metalworking fluids. The heat and force involved in fabrication alter these fluids, leaving a residue that can be very difficult to remove and can interfere with subsequent surface finishing. Even water-soluble lubes can leave a residue that is not water-soluble. In addition, when the residue of metalworking fluid is trapped in blind holes or crevices, it can leach out gradually over time. A part may look clean initially, but it may become contaminated over the course of days or even weeks. Therefore, parts held in inventory or received from suppliers or customers may show surface defects after finishing unless they are appropriately cleaned.
To avoid such coating problems, some suppliers and shops have used vapor degreasers. nPB has been widely used, in part because it has not been subject to the constraints of the National Emission Standard for Hazards Air Pollutants (NESHAP). These constraints include equipment design, practices during the cleaning process and recordkeeping. Other shops and suppliers use what is often referred to as the “NESHAP solvents” — MC, TCE and PCE. Most degreasers, including those with a cover, are considered “open top”; if the cover is opened, there can still be chemical vapor and/or liquid present.
A few manufacturers use “airless” or “airtight” degreasers that provide excellent containment of the solvent, with very low emissions to the environment and very low worker exposure. In an airless system, if a worker opens the top to add or remove parts, there is no detectable solvent liquid or vapor. The terminology for airless systems has been around for some time. Definitions are not necessarily clear or universal. It will be helpful when a clear definition of an airless system is developed for regulatory documents, one that involves both structural descriptions and functional performance. Airless systems incur a significant capital investment and, because they are more complex in design, they must be carefully maintained, much more so than would an open-top degreaser.
As of the time of writing this, a quantifiable exposure level associated with “unreasonable” has not been published. It is logical that these numbers are likely to be lower, perhaps much lower than those published by groups such as OSHA, the American Industrial Hygiene Association (AIHA) or the America Conference of Governmental Industrial Hygienists (ACGIH). These critical levels are likely to be different among the four solvents. Until these levels are established, it is difficult to determine conditions where there would not be an unreasonable risk.
So, what might happen? An outright ban on the use of all four of the solvents is possible but unlikely. There are fewer Draconian scenarios. For example, a manufacturer might be able to use one of the four solvents in an airless system. It is possible (although it seems less likely) that an open-top degreaser could be allowed under certain conditions. Or the EPA might consider the risk of one or more of the four solvents to be excessive even in an “airless” degreaser. Manufacturers could move to trans-DCE for some applications; recall that the EPA is also doing a risk evaluation for trans-DCE. Solvents containing trans-DCE could be an option if they clean well and if the EPA determines that there is not an unreasonable risk. However, because it is flammable, trans-DCE is nearly always sold as blends with a hydrofluoroether (HFE) or hydro-fluoro olefin (HFO) (sometimes referred to as “designer solvents” because they are more expensive). HFE or HFO suppresses the flashpoint; the trans-DCE provides the bulk of the cleaning power. The price of the “designer solvents” means that they should be properly contained to avoid losing costly solvent to the air, so even with those solvents, an airless system might be the most economical, albeit still costly, solution. Even if they are allowed by regulation, trans–DCE blends may not be suitable, because the boiling point of such blends tends to be low relative to classic chlorinated or brominated solvents, and heat provides energy for active cleaning.
Some manufacturers involved in surface finishing feel they need not worry because providers of cleaning agents will modify the course of regulatory reform or come up with a magic, cost-effective substitute. Suppliers already offer chemicals which they consider to be substitutes. The new cleaning agents may have a similar name as the one currently being used, but may have different physical and chemical properties, different costs or require new cleaning equipment.
While it is not necessary to immediately change the cleaning process, it is wise to think about other cleaning options, including aqueous processes and flammable solvents in specially designed cleaning machines. All involve process selection, evaluation and development. Most involve investment in new equipment; there may be increased costs for facility updates, insurance and permits. Many suppliers offer testing and evaluation of their own product lines. But surface finishers will still have to do the leg work (and the brain work).
About the Authors
Barbara and Ed Kanegsberg of BFK Solutions are expert consultants in surface quality and process development. Since 1994, they have been working with manufacturers to improve the value of their product through critical and precision cleaning. They are co-editors of and contributors to the two-volume “Handbook For Critical Cleaning,” second edition. Contact them at 310-459-3614 or firstname.lastname@example.org.
Computerized Measurement of Contact Angles
The measurement of the contact angle formed by a droplet of liquid placed on a horizontal surface – the so-called sessile drop – has been of interest to scientists and others for at least 200 years. These in turn can provide information on surface contamination or the wettability of a surface.